The Master draws upon a high-level faculty of international academicians and practitioners with consolidated experience in areas closely connected to the law and government of the European Union.
- Maria Giulia Amadio Viceré – Post-Doctoral Researcher in Political Science – LUISS Guido Carli
- Giuliano Amato – Judge – Italian Constitutional Court
- Leonard Besselink – Full Professor of Constitutional Law - University of Amsterdam
- Sven Biscop – Director – Europe in the World programme at the Egmont - Royal Institute for International Relations (Brussels)
- Christian Blasberg – Adjunct Professor of European Political History – LUISS Guido Carli
- Simon Bulmer – Full Professor of European Politics – University of Sheffield
- Daniele Caviglia – Associate Professor of History and International Relations – Università degli Studi Internazionali di Roma
- Luisa Corazza – Full Professor of Labour Law – University of Molise
- Luigi Daniele – Full Professor of EU Law – University of Rome Tor Vergata
- Sergio Fabbrini – Full Professor of Politics and International Relations at LUISS Guido Carli and Dean of the LUISS Department of Political Science
- Daniele Gallo – Full Professor of EU Law – LUISS Guido Carli ()
- Adrienne Héritier – Emeritus Professor of Comparative and European Public Policy – European University Institute
- Marc Jaeger – President and Judge – General Court of the European Union
- Robert Leonardi – Director – Economic and Social Cohesion Laboratory
- Marco Margheri – Executive Vice-President for Institutional Affairs – Edison
- Fabrizio Marrella – Full Professor of International and EU Law – Ca’ Foscari University of Venice
- Bernardo Giorgio Mattarella – Full Professor of Administrative Law – LUISS Guido Carli
- Massimo Orzan – Legal Secretary – Cabinet of the President of the General Court of the European Union
- Tom Ottervanger – Professor Emeritus of European Law and Dutch Competition Law and antitrust specialist at Allen & Overy – Leiden University
- Stefania Panebianco – Associate Professor of Political Science – University of Catania
- Marco Piantini – Adviser to Italy’s Prime Minister for European Affairs – Presidency of the Council of Ministers
- Vivien Schmidt – Full Professor of International Relations and Political Science – Boston University
- Robert Schütze – Full Professor of European Union Law – Durham University
- Mark Thatcher – Full Professor of International Public Policies – LUISS Guido Carli
- Gian Luigi Tosato – Emeritus Professor of International and EU Law – University La Sapienza Rome
- Jan Wouters – Full Professor of International Law and International Organiyations, Jean Monnet Chair ad personam EU and Global Governance – KU Leuven